Frontispiece: C−F Bond Activation Mediated by Phosphorus Compounds

E–H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound

The synthesis of a phosphorus(III) compound bearing a N,N-bis(3,5-di-tert-butyl-2-phenoxy)amide ligand is reported. This species has been found to react with ammonia and water, activating the E-H bonds in both substrates by formal oxidative addition to afford the corresponding phosphorus(V) compounds. In the case of water, both O-H bonds can be activated, splitting the molecule into its constit...

Early-transition-metal-mediated activation and transformation of white phosphorus.

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Selective Metal - Mediated C - C Bond Activation of Strain Compounds : Application to Challenging non - Natural Product Synthesis

Phosphorus Compounds in Animal Tissues

The concept that nucleic acids are intimately associated with fundamental cellular processes has gained considerable favor within the last few years. This can undoubtedly be attributed to the researches of Caspersson and his associates. Caspersson, with the aid of ultraviolet spectrophotometry, has been able to measure the nucleic acids in various parts of the cell under a variety of experiment...

Phosphorus Compounds in the Cell

In the first paper in this series (Davidson, Frazer & Hutchison, 1951) it was emphasized that in experiments on the incorporation of radioactive phosphorus (32p) into the nucleic acids and their derivatives in the cell, it was essential, in order to obtain true specific activities, to separate the nucleotide fractions in a form free from all traces of highly active contaminants. The procedure o...